Three qubits in less than three baths: Beyond two-body system-bath interactions in quantum refrigerators
A. Ghoshal, S. Das, A. K. Pal, A. Sen, U. Sen
Physical Review A 104 (4), 42208 (2021).
We show that quantum absorption refrigerators, which have traditionally been studied as of three qubits, each of which is connected to a thermal reservoir, can also be constructed by using three qubits and two thermal baths, where two of the qubits, including the qubit to be locally cooled, are connected to a common bath. With a careful choice of the system, bath, and qubit-bath interaction parameters within the Born-Markov and rotating-wave approximations, one of the qubits attached to the common bath achieves a cooling in the steady state. We observe that the proposed refrigerator may also operate in a parameter regime where no or negligible steady-state cooling is achieved, but there is considerable transient cooling. The steady-state temperature can be lowered significantly by an increase in the strength of the few-body interaction terms existing due to the use of the common bath in the refrigerator setup. The proposed refrigerator built with three qubits and two baths is shown to provide steady-state cooling for both Markovian qubit-bath interactions between the qubits and canonical bosonic thermal reservoirs, and a simpler reset model for the qubit-bath interactions.
Resource theory of quantum coherence with probabilistically nondistinguishable pointers and corresponding wave-particle duality
C. Srivastava, S. Das, U. Sen
Physical Review A 103 (2), 22417 (2021).
"One of the fundamental features of quantum mechanics is the superposition principle, a manifestation of which is embodied in quantum coherence. Coherence of a quantum state is invariably defined with respect to a preferred set of pointer states, and there exist quantum coherence measures with respect to deterministically as well as probabilistically distinguishable sets of quantum state vectors. Here we study the resource theory of quantum coherence with respect to an arbitrary set of quantum state vectors, that may not even be probabilistically distinguishable. Geometrically, a probabilistically indistinguishable set of quantum state vectors forms a linearly dependent set. In quantum optics, the coherent states form an ""overcomplete basis"" of linearly dependent states and are useful in dealing with states that can be prepared in optical systems. Also, the resource theory of magic can be looked upon as a resource theory of quantum coherence with respect to a set of basis vectors that are probabilistically indistinguishable. These motivate us to consider a resource theory of coherence with respect to probabilistically indistinguishable pointers. We find the free states of the resource theory, and analyze the corresponding free operations, obtaining a necessary condition for an arbitrary quantum operation to be free. We identify a class of measures of the quantum coherence and, in particular, establish the monotonicity property of the measures. We find a connection of an arbitrary set of quantum state vectors with positive operator-valued measurements with respect to the resource theory being considered, which paves the way for an alternate definition of the free states. We subsequently examine the wave-particle duality in a double-slit setup in which superposition of probabilistically indistinguishable quantum state vectors is possible. Specifically, we report a complementary relation between quantum coherence and path distinguishability in such a setup."
Concept of Orbital Entanglement and Correlation in Quantum Chemistry
L. X. Ding, S. Mardazad, S. Das, S. Szalay, U. Schollwöck, Z. Zimboras, C. Schilling
Journal of Chemical Theory and Computation 17 (1), 79-95 (2021).
A recent development in quantum chemistry has established the quantum mutual information between orbitals as a major descriptor of electronic structure. This has already facilitated remarkable improvements in numerical methods and may lead to a more comprehensive foundation for chemical bonding theory. Building on this promising development, our work provides a refined discussion of quantum information theoretical concepts by introducing the physical correlation and its separation into classical and quantum parts as distinctive quantifiers of electronic structure. In particular, we succeed in quantifying the entanglement. Intriguingly, our results for different molecules reveal that the total correlation between orbitals is mainly classical, raising questions about the general significance of entanglement in chemical bonding. Our work also shows that implementing the fundamental particle number superselection rule, so far not accounted for in quantum chemistry, removes a major part of correlation and entanglement seen previously. In that respect, realizing quantum information processing tasks with molecular systems might be more challenging than anticipated.